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Select the top CH3 group
Click once on the top carbon atom
Use the 'Select Connected' menu command from the Edit menu

ADFinput ethanol top selected

As you will notice, all atoms directly connected to the selected atom are added to the selection. Alternatively, you can also make a selection by shift-clicking on the elements you want to select.

Click in empty space
Click on the top carbon atom
Shift-Click once (without moving) on each of the top hydrogen atoms

This has almost the same effect (in this case you have not selected the second carbon atom).

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