Barium (V, 4p frozen)
 
BASIS
1S   36.800
2S   24.200
3S   11.300
4S    8.000
2P   25.750
3P   12.450
4P    7.300
3D   14.350

        1S  106.300
5S    4.000
5S    2.550
6S    1.750
6S    1.150
6S     .780
5P    3.700
5P    2.500
5P    1.750
6P    1.150
4D    7.750
4D    5.000
4D    3.450
5D    2.200
5D    1.100
4F    5.000
4F    2.000
END
 
CORE    4  3  1  0
        1S  427.000
        1S  106.300
        1S   57.500
        2S   64.900
        2S   24.800
        3S   13.200
        3S   10.000
        4S    9.750
        4S    6.200
        5S    4.000
        5S    2.550
        6S    1.750
        6S    1.150
        6S     .780
        2P   38.100
        2P   23.900
        3P   14.000
        3P   10.650
        4P    7.800
        4P    5.300
        5P    3.700
        5P    2.500
        5P    1.750
        3D   18.050
        3D   10.850
        4D    7.750
        4D    5.000
        4D    3.450
END
 
DESCRIPTION
    .11373609102224768383E-01   .86833536086007245824E-01
    .93007151379566288529E+00  -.11585462054878125845E-01
    .12163506853406311908E-02  -.41531013700343748576E-02
    .68532806640778246368E-02  -.38992749915521219758E-02
    .68297583751768416432E-03  -.25677783414214085589E-03
    .15691719324424481335E-03  -.89470419233557410750E-04
    .56338090287532646737E-04  -.21131105415008863202E-04

   -.33411877016894029994E-02  -.75171847217431211896E-01
   -.19625961083264162332E+00  -.18402335794592131202E+00
    .11174615195336645712E+01   .21193140004194827714E-01
   -.38115215637354593614E-01   .24648675562397099476E-01
   -.56525258010274919904E-02   .24341550156313663394E-02
   -.15573033676764204587E-02   .91026995404054611687E-03
   -.57900960438139336024E-03   .21818864070725086366E-03

    .11185103051405288072E-02   .68370890420563754097E-01
    .71906926234318480767E-02   .16834112480618240726E+00
   -.68076900467442180709E+00   .79570762777675474453E+00
    .66473213816147069810E+00  -.37742747944513260761E+00
    .82293212602230991770E-01  -.34647072435994935580E-01
    .22141436290996716757E-01  -.12986434303412393992E-01
    .82853102666067147269E-02  -.31284389490432852436E-02

   -.50414456378712049420E-03  -.35399050121749417452E-01
    .33642952762967569605E-02  -.87620204756397770951E-01
    .34157383457518314396E+00   .14164671481873470152E-01
   -.16306206325263494783E+01   .15000391221475448678E+01
    .62690240755211878998E+00   .19458250856122918937E-01
   -.12090794996109927376E-01   .77489456888076083119E-02
   -.51715547583642646964E-02   .19990843513713451446E-02

    .21329134889297321487E+00   .80649273519242803410E+00
    .10576517252775970851E-01  -.12582106489151020923E-01
    .91115023457743297974E-02  -.64100352686617496564E-02
    .35518966220105929049E-02  -.23471530328490705121E-02
    .84374222763821001263E-03

   -.73689129508912515343E-01  -.46268285724196661635E+00
    .76369453247733809498E+00   .39989760586134726061E+00
   -.18466818870571777289E-01   .12214948161469407067E-01
   -.67238338775726025007E-02   .44883085463203447468E-02
   -.16289619589640218569E-02

    .29579823518368415780E-01   .22795089599409879000E+00
   -.40386100101829702780E+00  -.34139023622480729747E+00
    .82594961856337745232E+00   .42955187863636212775E+00
    .97468943636819429382E-02  -.68764663269392234390E-02
    .28908967625974838628E-02

    .40898284247634697497E+00   .64711218264684600143E+00
   -.11052981595215432414E-01   .79216473383099499095E-02
   -.20969051938893087245E-02
0/
END
 
FIT
 1S  73.60
 1S  45.46
 2S  51.91
 2S  35.76
 3S  36.12
 3S  26.37
 4S  25.43
 4S  19.27
 5S  18.17
 5S  14.14
 6S  13.18
 6S  10.46
 7S   9.68
 7S   7.81
 8S   7.20
 8S   5.89
 9S   5.41
 9S   4.47
10S   4.11
10S   3.43
10S   2.86
11S   2.62
11S   2.21
11S   1.86
11S   1.56
 2P  62.55
 3P  53.32
 4P  44.49
 5P  36.89
 5P  25.41
 6P  21.06
 6P  14.95
 7P  12.42
 7P   9.03
 8P   7.52
 8P   5.57
 9P   4.66
 9P   3.51
10P   2.95
10P   2.25
 3D  51.50
 4D  38.65
 5D  29.16
 6D  22.18
 7D  17.01
 7D  11.45
 8D   8.85
 8D   6.10
 9D   4.76
 9D   3.35
10D   2.63
10D   1.88
 4F  40.10
 5F  25.41
 6F  16.48
 7F  10.91
 8F   7.35
 8F   4.43
 9F   3.03
 9F   1.88
 5G  28.70
 6G  16.73
 7G  10.03
 8G   6.16
 9G   3.87
 9G   2.20
END
 
FITCOEFFICIENTS
   .244032333801472333E+03  -.158167784230725204E+03  -.144151993902065078E+05
   .150057994834900619E+05  -.137314840493046708E+06   .274031303757712294E+04
  -.110089383605540032E+06   .114168489004876246E+06  -.318997053510675090E+06
   .109179742039646717E+05   .539162851130467461E+05  -.472913164005077215E+04
  -.256374454772372428E+04  -.764372703124690531E+02   .193805579701657052E+03
   .519588063964047038E+02   .164243316705022391E+01   .629286537170188787E+00
  -.411205240381761553E-01   .487420651886489881E-02   .305361171872334919E-03
   .266941440206203017E-04   .167646128991403562E-05   .583743149576489167E-07
   .525884705309253071E-09
/
END