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Date: Sat, 17 Jun 2006 07:00:00 +0200
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Forum: ADF and ADF-GUI discussions

Topic: How to fix this kind of error in freq calcs.

LinkPost TimeAuthorMessage Excerpt
20216 Jun 2006, 02:06 PM CESTbluemoleculeHi, all

Have you met the similar error shown below in freq calculations ?

Frequency Dipole Strength Absorption Intensity (degeneracy not counted)
cm-1 1e-40 esu2 cm2 km/mole
-------- ---------- ----------
-1578.281080, 534370.510851, -211399.961600

78.340936, 17973.009116 , 352.929224

155.732862 , 38.693240 , 1.510405

231.360224, 16439.096878 , 953.333207

952.961195 , 3210.699138, 766.925005

2121.398771 , 22188.572431 , 11798.580081


I'm looking for a minimum which is to be verifyed by freq calculation.
Unfortunately, some unknown error has happend in freq calculations so that I cannot judge the results correctly. I have met this situation twice and last time I fixed it by adding "lshift" in SCF block while this time the same setting doesn't works.

the frontier MO are shown below:

AA 10 A 1.00 -0.24049510393872E+00 -6.5442
AA 10 B 1.00 -0.23934301666105E+00 -6.5129
AA 11 A 1.00 -0.13414948283151E+00 -3.6504
AAA 4 A 0.00 -0.13374206751979E+00 -3.6393
AAA 4 B 0.00 -0.12800319846104E+00 -3.4831


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Received on 2006-06-17 07:00:01

This archive was generated by hypermail 2.2.0 : 2006-11-02 07:00:02 CET