Vanadium (II, 2p frozen) BASIS 1S 17.75 2S 8.20 2P 9.35 3S 2.95 3S 4.55 3P 2.70 3P 4.40 3D 1.14 3D 2.50 3D 5.30 4S 0.95 4S 1.65 4P 1.26 END CORE 2 1 0 0 1S 28.55 1S 21.25 2S 8.75 2S 6.20 3S 5.05 3S 3.15 4S 0.84 4S 1.28 4S 2.05 2P 12.40 2P 7.75 3P 4.40 3P 2.65 END DESCRIPTION .24261946942472378819E+00 .75983815749099559156E+00 .31951933863151538162E-01 -.41021387260947665687E-01 .23353794768155092254E-01 -.10511269882997416672E-01 .11049618970386308834E-02 -.29886568364417753427E-02 .47207446257881736928E-02 .71818191709305909121E-01 -.44625002072093544747E+00 .99858025297661823227E+00 .11781255649935576391E+00 -.51843544217613828085E-01 .28985480334837505911E-01 -.37728781992534699691E-02 .99473526554696330149E-02 -.14892443725125388554E-01 .37532475578407753503E+00 .65393667814564615526E+00 .46153499560086519438E-02 -.20908354356248891152E-02 0/ END FIT 1S 36.20 2S 34.78 3S 30.73 4S 26.44 4S 18.01 5S 15.35 5S 10.85 6S 9.22 6S 6.70 6S 4.87 7S 4.14 7S 3.08 7S 2.29 7S 1.70 2P 27.45 3P 17.79 4P 11.72 5P 7.88 6P 5.39 6P 3.18 7P 2.21 3D 23.40 4D 14.91 5D 9.72 6D 6.47 6D 3.72 7D 2.52 4F 14.65 5F 8.40 5F 4.05 6F 2.40 5G 9.10 5G 4.81 5G 2.54 END FITCOEFFICIENTS .985803795727220E+02 -.936441091018922E+03 -.311247381576673E+03 .931808985431206E+05 .198428663827058E+05 -.500924827182774E+05 .265823794356116E+04 .442157128320451E+04 .250376783485387E+03 .256149926480539E+01 .539426985596665E+00 .579730236872440E-01 .279419183686220E-02 .162132792375209E-04 .000000000000000E+00 / END