Vanadium (V, 2p frozen) BASIS 1S 18.10 2S 7.90 2P 9.35 3S 3.20 3S 4.95 3P 5.100 3P 3.450 3P 2.350 3D 1.14 3D 2.50 3D 5.30 4S 0.85 4S 1.30 4S 2.10 4P 1.26 4F 2.400 END CORE 2 1 0 0 1S 28.55 1S 21.25 2S 8.75 2S 6.20 3S 5.05 3S 3.15 4S 0.84 4S 1.28 4S 2.05 2P 12.40 2P 7.75 3P 4.40 3P 2.65 END DESCRIPTION .24261946942472378819E+00 .75983815749099559156E+00 .31951933863151538162E-01 -.41021387260947665687E-01 .23353794768155092254E-01 -.10511269882997416672E-01 .11049618970386308834E-02 -.29886568364417753427E-02 .47207446257881736928E-02 .71818191709305909121E-01 -.44625002072093544747E+00 .99858025297661823227E+00 .11781255649935576391E+00 -.51843544217613828085E-01 .28985480334837505911E-01 -.37728781992534699691E-02 .99473526554696330149E-02 -.14892443725125388554E-01 .37532475578407753503E+00 .65393667814564615526E+00 .46153499560086519438E-02 -.20908354356248891152E-02 0/ END FIT 1S 36.20 2S 34.78 3S 30.73 4S 26.44 4S 18.01 5S 15.35 5S 10.85 6S 9.22 6S 6.70 6S 4.87 7S 4.14 7S 3.08 7S 2.29 7S 1.70 2P 27.45 3P 17.79 4P 11.72 5P 7.88 6P 5.39 6P 3.18 7P 2.21 3D 23.40 4D 14.91 5D 9.72 6D 6.47 6D 3.72 7D 2.52 4F 14.65 5F 8.40 5F 4.05 6F 2.40 5G 9.10 5G 4.81 5G 2.54 END FITCOEFFICIENTS .991668213283681297E+02 -.972024013506494839E+03 .154714196326445006E+03 .905742637578836584E+05 .202917446636487330E+05 -.506233980222925384E+05 .269318619158988940E+04 .442309558722955444E+04 .249473759340232021E+03 .243505737127459021E+01 .628835373524958552E+00 .481806874567107732E-01 .332799799019417543E-02 .395306648013184731E-05 .000000000000000000E+00 / END